Display omitted
•High level of ∑OPEs was detected in the northwest shore of Taihu Lake.•TCIPP and TCEP predominated in the Taihu Lake waters.•∑OPEs decreased from northwest to southeast Taihu ...Lake.•Calculated logKoc of OPEs displayed significantly correlation with their logKow.•OPEs manufacturing in Yixing was an important point source of OPEs in Taihu Lake.
Taihu Lake is the third largest freshwater lake in China, and has been heavily polluted by surrounding industrial activities. This study aimed to investigate the sources of organophosphate esters (OPEs) in Taihu Lake, and their partitioning behaviors between sediment and water. The total concentrations of the eleven target OPEs (∑OPEs) in the water and sediment of Taihu Lake were 166–1530 ng/L and 2.82–47.5 ng/g dw, respectively. The ∑OPEs in both water and sediment generally decreased from northwest to southeast. Extremely high level of ∑OPEs (1410–15,300 ng/L) was found in the flow-in rivers passing through the OPE manufacturing regions in Yixing. In both water and sediment, tris(2-chloroisopropyl) phosphate and tris(chloroethyl) phosphate were the predominant OPEs. The sediment-water partitioning coefficients, log Koc, of OPEs were calculated based on paired sediment and water samples, and they displayed strong correlation with their log Kow (octanol-water), suggesting that their partition was dominated by hydrophobic interaction. Principle component analysis indicated that OPE manufacturing in Yixing was an important point source of OPEs, especially of TCIPP in Taihu Lake. Many OPE-related industries, such as electronic, textile, machine and plastic industries around Taihu Lake also made contributions to OPEs in the Lake.
Asphalt roads are the basic component of a land transportation system, and the quality of asphalt roads will decrease during the use stage because of the aging and deterioration of the road surface. ...In the end, some road pavement distresses may appear on the road surface, such as the most common potholes and cracks. In order to improve the efficiency of pavement inspection, currently some new forms of remote sensing data without destructive effect on the pavement are widely used to detect the pavement distresses, such as digital images, light detection and ranging, and radar. Multispectral imagery presenting spatial and spectral features of objects has been widely used in remote sensing application. In our study, the multispectral pavement images acquired by unmanned aerial vehicle (UAV) were used to distinguish between the normal pavement and pavement damages (e.g., cracks and potholes) using machine learning algorithms, such as support vector machine, artificial neural network, and random forest. Comparison of the performance between different data types and models was conducted and is discussed in this study, and indicates that a UAV remote sensing system offers a new tool for monitoring asphalt road pavement condition, which can be used as decision support for road maintenance practice.
The bioavailability and biomagnification of organophosphate esters (OPEs) were investigated in a food web in the Zhushan Bay of Taihu Lake, China. The organisms included mainly three biological ...groups: plankton, invertebrates, and fish, which displayed distinctly different compositional profiles of OPEs. In general, the log BAFs (bioaccumulation factor) of OPEs displayed a significant correlation with their log Kow (octanol-water partitioning coefficient), suggesting that the bioaccumulation was mainly controlled by the hydrophobicity. The log BAFs of the more hydrophobic OPEs in benthic invertebrates were higher than in fish, suggesting that ingesting sediment constituted additional exposure route for benthic invertebrates. The log BSAFs (biota-sediment accumulation factor) in the benthic invertebrates increased with log Kow in the range of 1.44–5.73 and decreased afterwards. The depressed bioavailability of the highly hydrophobic OPEs was attributed to their strong adsorption to the sediment. The biomagnification potency of OPEs was affected by hydrophobicity of the compounds and biotransformation properties in the organisms at different trophic levels. 2-Ethylhexyl diphenyl phosphate biomagnified in the fish food web of Taihu Lake with a TMF (trophic magnification factor) of 3.61, which was due to the combined results of its relatively high hydrophobicity (log Kow of 5.73) and decreased metabolism potential in the high-trophic-level fish. The constant metabolism diminished the biomagnification potency of hydrophobic compounds triphenyl phosphate and tricresyl phosphate in this food web.
Display omitted
•Plankton, invertebrates, and fish displayed distinctly different OPE profiles.•Log BAFs of hydrophobic OPEs in benthic invertebrates were higher than in fish.•Parabolic relationship was obtained between log BSAF and log Kow for OPEs.•The OPE biomagnification was also affected by metabolisms in different organisms.•EHDPP biomagnified in the fish food web of Taihu Lake with a TMF of 3.61.
Display omitted
•Most OPEs tend to bind with plasma proteins, such as human serum albumin.•Metabolism and binding with plasma proteins affect the clearance rates of OPEs.•Extrapolation from the in ...vitro microsomal intrinsic clearance method is feasible.•Half-lives of Cl-OPEs are longer than those of the aryl- and alkyl-OPEs.
The renal and hepatic clearance rates of organophosphate esters (OPEs) in humans were estimated. Six OPEs and their corresponding diester metabolites (mOPEs) were quantified respectively in 30 paired human plasma and urine samples collected in Hengshui, Hebei province, China. The renal clearance rate (CLrenal) of triphenyl phosphate (TPHP), tris(chloroethyl) phosphate (TCEP) and tris(1,3-dichloro-isopropyl) phosphate (TDCIPP) was estimated to be 68.9, 50.9 and 33.3 mL/kg/day, respectively, while it was not calculated for other three OPEs due to the low detection frequencies in human samples. To estimate the clearance rates of the target OPEs, hepatic clearance rates (CLh) of OPEs were extrapolated from their in vitro intrinsic clearance data in human liver microsomes (CLHLM). The calculated CLh values of TCEP and TDCIPP were comparable to their CLrenal, indicating that the in vitro extrapolation method was suitable for estimating the clearance rates of OPEs. The higher binding affinity of TDCIPP with plasma proteins could reduce its renal clearance. The estimated half-lives of Cl-OPEs in human were longer than those of the aryl- and alkyl-OPEs. This study provided a feasible in vitro method to predict the clearance and half-lives of OPEs in human, which is significant for their accurate health risk assessment.
This paper presents a study of the removal of ammonium ion from aqueous solutions using natural Chinese (Chende) zeolite. A series of experiments was conducted to examine the effects of solution pH, ...particle size, contact time, adsorbent dosage, and the presence of other cation- and anion species on ammonium removal. The findings indicated that these parameters named had a significant effect on the removal of ammonium by the zeolite. The effect of other cations on the removal of ammonium followed the order of preference Na
+
>
K
+
>
Ca
2+
>
Mg
2+ at identical mass concentrations, and the effect of the presence of individual anions followed the order of preference carbonate
>
chloride
>
sulfate
>
phosphate at identical mass concentrations of ammonium ions. Kinetic analysis showed that the adsorption of ammonium on zeolite at different ranges of particle size well followed the pseudo-second-order model and followed the intra-particle diffusion model only during the initial 60
min of the adsorption process. Equilibrium isotherm data was fitted to the linear Langmuir- and Freundlich models with the latter model providing the better description of the process (
R
2
=
0.991–0.997) compared to the former (
R
2
=
0.902–0.989).
► PFCs are widely present in surface water and sediment of Liao River and Taihu Lake. ► PFOS and PFOA are at similar level to that in the rivers, Japan but lower than in Great Lakes. ► PFOS and long ...chain PFCAs prefer to partition in sediment. ► Log
K
oc
s of PFHxS, PFOS and PFOA are significantly lower than PAHs, HCHs and DDTs.
The concentrations of four perfluorinated sulfonate acids (PFSAs) and 10 perfluorinated carboxylate acids (PFCAs) were measured in water and sediment samples from Liao River and Taihu Lake, China. In the water samples from Taihu Lake, PFOA and PFOS were the most detected perfluorinated compounds (PFCs); in Liao River, PFHxS was the predominant PFC followed by PFOA, while PFOS was only detected in two of the samples. This suggests that different PFC products are used in the two regions. PFOS and PFOA in both watersheds are at similar level as in the rivers of Japan, but significantly lower than in Great Lakes. The contributions of PFOS and long chain PFCAs in sediments were much higher than in water samples of both watersheds, indicating preferential partition of these PFCs in sediment. The concentrations of PFOS and PFOA were three orders of magnitude of lower than that of polycyclic aromatic hydrocarbons in the same sediments. The average sediment–water partition coefficients (log
K
oc
) of PFHxS, PFOS and PFOA were determined to be 2.16, 2.88 and 2.28 respectively.
Display omitted
•Target compounds elicited hepatic steatosis in zebrafish larvae.•Cl-PFOS, 6:2 Cl-PFESA and PFOS disrupted lipid metabolism similarly.•8:2 Cl-PFESA triggered a different lipid ...modulation pattern.•Mode-of-hepatotoxicity was predominantly dependent on carbon chain length.
Hepatotoxicity in zebrafish (Danio rerio) larvae elicited by legacy perfluorooctane sulfonate (PFOS) and its three novel chlorinated alternatives, including chlorinated polyfluorooctane sulfonate (Cl-PFOS) and chlorinated polyfluoroalkyl ether sulfonates (6:2 and 8:2 Cl-PFESA analogs), was evaluated in this study. Upon 7-day separate exposure to the four target compounds at 1 µmol/L, significant hepatic steatosis in exposed larvae was evidenced by pathological micro/macro vacuolation, which was presumably attributed to the excess accumulation of lipid, especially the overloaded triglyceride (TG) level. Disruption on gene transcription was subjected to a structure-dependent manner. In general, PFOS, Cl-PFOS and 6:2 Cl-PFESA of the identical carbon chain length (i.e. C8), despite with different substituents, displayed a similar activation mode and comparable disruptive potency on lipid metabolism responsive genes, which particularly promoted fatty acid synthesis (acetyl-CoA carboxylase, acacb) and β-oxidation (cytochrome P450 enzymes-1A, cyp1a; peroxisomal acyl-CoA oxidase 1, acox1; and acyl-CoA dehy-drogenase, acadm). However, 8:2 Cl-PFESA with a prolonged carbon chain length (i.e. C10), preferentially disturbed fatty acid exportation (apolipoprotein-B100, apob) and triggered a different modulation pattern on fatty acid β-oxidation against the other three compounds. Molecular docking analysis indicated that 8:2 Cl-PFESA exhibited considerably higher peroxisome proliferator-activated receptors (PPARs) antagonism than others, corresponding to its unique suppression effect on fatty acid β-oxidation responsive genes. To our knowledge, this is the first in vivo study reporting hepatotoxicity of Cl-PFOS and Cl-PFESAs to aquatic organisms. Although characterized with different toxic mode-of-action, these novel alternatives can elicit hepatic steatosis as strong as PFOS, stressing the biological risks in view of their global contamination.
As a new alternative to perfluorooctane sulfonate (PFOS), 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB) has been currently used in industrial and consumer applications, which has been ...frequently detected in environment media. However, the behaviors of 6:2 FTAB in plants are still unclear. This study investigated the bioaccumulation, biotransformation and ecotoxicity of 6:2 FTAB in wheat (Triticum aestivum L.) by hydroponic exposure. 6:2 FTAB was easily taken up by roots with the root concentration factor (RCF) as high as 94.8, but difficult to be acropetally translocated in the shoots with the translocation factor (TF) as low as 0.058. Two intermediates and six terminal perfluorocarboxylic acid (PFCA) metabolites were detected in roots and shoots. The detected metabolites included 6:2 fluorotelomer sulfonic acid (6:2 FTSA), 6:2 fluorotelomer carboxylic acid (6:2 FTCA), perfluoroheptanoic acid (PFHpA), perfluorohexanoic acid (PFHxA), perfluoropentanoic acid (PFPeA), perfluorobutyric acid (PFBA), pentafluoropropionic acid (PFPrA) and trifluoroacetic acid (TFA), and 6:2 FTSA was the main metabolite. 6:2 FTAB significantly reduced the biomass of plant and prevented chlorophyll (Chl) accumulation, while caused no significant change in malondialdehyde (MDA) content. Significant reduction in glutathione (GSH) contents, excess production of reactive oxygen species (ROS), and obvious inhibition of superoxide dismutase (SOD), catalase (CAT), peroxidase (POD) and glutathione-s-transferase (GST) activities were observed, suggesting damage of antioxidant defense systems and failure to detoxication of 6:2 FTAB in wheat. These findings provide important knowledge for the fate of 6:2 FTAB in plants.
Display omitted
•6:2 FTAB was taken up by root efficiently but translocated to shoot difficultly.•6:2 FTSA, 6:2 FTCA, PFHpA, PFHxA, PFPeA, PFBA, PFPrA, TFA were detected in plant.•6:2 FTSA was the main metabolite in wheat root and shoot.•6:2 FTAB caused growth inhibition and antioxidative defense system damage in plant.
SRTM DEM and its application advances Yang, Liping; Meng, Xingmin; Zhang, Xiaoqiang
International journal of remote sensing,
01/2011, Letnik:
32, Številka:
14
Journal Article
Recenzirano
The Shuttle Radar Topography Mission (SRTM) provides for the first time a near-global high-resolution digital elevation model (DEM) with great advantages of homogeneous quality and free availability. ...The last 10 years or so have seen rapid advances in the data processing and applications of SRTM DEM. From the perspective of SRTM, we present in this article a brief overview of the principles, datasets, void filling and accuracy of SRTM DEM first. Special emphasis is on its application advances in various research fields including, but not limited to, geology, geomorphology, water resources and hydrology, glaciology, evaluation of natural hazards and vegetation surveys. Problems that arose from the applications and the future research interests are also addressed. We hope this study will greatly facilitate the ease of use of SRTM DEM in extensive fields.
PDF
