Manipulating the surface energy, and thereby the wetting properties of solids, has promise for various physical, chemical, biological and industrial processes. Typically, this is achieved by either ...chemical modification or by controlling the hierarchical structures of surfaces. Here we report a phenomenon whereby the wetting properties of vermiculite laminates are controlled by the hydrated cations on the surface and in the interlamellar space. We find that vermiculite laminates can be tuned from superhydrophilic to hydrophobic simply by exchanging the cations; hydrophilicity decreases with increasing cation hydration free energy, except for lithium. The lithium-exchanged vermiculite laminate is found to provide a superhydrophilic surface due to its anomalous hydrated structure at the vermiculite surface. Building on these findings, we demonstrate the potential application of superhydrophilic lithium exchanged vermiculite as a thin coating layer on microfiltration membranes to resist fouling, and thus, we address a major challenge for oil-water separation technology.
Vegetation water content is one of the important biophysical features of vegetation health, and its remote estimation can be utilized to real-timely monitor vegetation water stress. Here, we compared ...the responses of canopy water content (CWC), leaf equivalent water thickness (EWT), and live fuel moisture content (LFMC) to different water treatments and their estimations using spectral vegetation indices (VIs) based on water stress experiments for summer maize during three consecutive growing seasons 2013-2015 in North Plain China.
Results showed that CWC was sensitive to different water treatments and exhibited an obvious single-peak seasonal variation. EWT and LFMC were less sensitive to water variation and EWT stayed relatively stable while LFMC showed a decreasing trend. Among ten hyperspectral VIs, green chlorophyll index (CI
), red edge normalized ratio (NR
), and red-edge chlorophyll index (CI
) were the most sensitive VIs responding to water variation, and they were optimal VIs in the prediction of CWC and EWT.
Compared to EWT and LFMC, CWC obtained the best predictive power of crop water status using VIs. This study demonstrated that CWC was an optimal indicator to monitor maize water stress using optical hyperspectral remote sensing techniques.
The gastrointestinal (GI) microbiota of vertebrates plays critical roles in nutrition, development, immunity and resistance against invasive pathogens. In the past decade, research of the GI ...microbiota of mammals has drastically increased our knowledge on the microbiota and their relationship with health and disease. However, our understanding of fish intestinal microbiota is limited. This review provides an overview of research on fish gut microbiota, including microbial composition, formation, factors that affect the GI microbes and characteristics of fish intestinal microbiota compared with human and mice. Further, the updated research on gnotobiotic zebrafish is elaborated and the insights gained on functions of the fish intestinal microbiota are discussed. Understanding the intestinal microbiota of fish will guide the development of probiotics, prebiotics and hopefully probiotic effectors as novel additives to improve the health of fish.
Fresh meat is a highly perishable product due to its biological composition. Many interrelated factors influence the shelf life and freshness of meat such as holding temperature, atmospheric oxygen ...(O
2), endogenous enzymes, moisture, light and most importantly, micro-organisms. With the increased demand for high quality, convenience, safety, fresh appearance and an extended shelf life in fresh meat products, alternative non-thermal preservation technologies such as high hydrostatic pressure, superchilling, natural biopreservatives and active packaging have been proposed and investigated. Whilst some of these technologies are efficient at inactivating the micro-organisms most commonly related to food-borne diseases, they are not effective against spores. To increase their efficacy against vegetative cells, a combination of several preservation technologies under the so-called hurdle concept has also been investigated. The objective of this review is to describe current methods and developing technologies for preserving fresh meat. The benefits of some new technologies and their industrial limitations is presented and discussed.
Superhydrophobic coatings have tremendous potential for applications in different fields and have been achieved commonly by increasing nanoscale roughness and lowering surface tension. Limited by the ...availability of either ideal nano-structural templates or simple fabrication procedures, the search of superhydrophobic coatings that are easy to manufacture and are robust in real-life applications remains challenging for both academia and industry. Herein, we report an unconventional protocol based on a single-step, stoichiometrically controlled reaction of long-chain organosilanes with water, which creates micro- to nano-scale hierarchical siloxane aggregates dispersible in industrial solvents (as the coating mixture). Excellent superhydrophobicity (ultrahigh water contact angle >170° and ultralow sliding angle <1°) has been attained on solid materials of various compositions and dimensions, by simply dipping into or spraying with the coating mixture. It has been demonstrated that these complete waterproof coatings hold excellent properties in terms of cost, scalability, robustness, and particularly the capability of encapsulating other functional materials (e.g. luminescent dyes).
A
bstract
We investigate neutrinoless double beta decay (0
νββ
) in the presence of sterile neutrinos with Majorana mass terms. These gauge-singlet fields are allowed to interact with Standard-Model ...(SM) fields via renormalizable Yukawa couplings as well as higher-dimensional gauge-invariant operators up to dimension seven in the Standard Model Effective Field Theory extended with sterile neutrinos. At the GeV scale, we use Chiral effective field theory involving sterile neutrinos to connect the operators at the level of quarks and gluons to hadronic interactions involving pions and nucleons. This allows us to derive an expression for 0
νββ
rates for various isotopes in terms of phase-space factors, hadronic low-energy constants, nuclear matrix elements, the neutrino masses, and the Wilson coefficients of higher-dimensional operators. The required hadronic low-energy constants and nuclear matrix elements depend on the neutrino masses, for which we obtain interpolation formulae grounded in QCD and chiral perturbation theory that improve existing formulae that are only valid in a small regime of neutrino masses. The resulting framework can be used directly to assess the impact of 0
νββ
experiments on scenarios with light sterile neutrinos and should prove useful in global analyses of sterile-neutrino searches. We per- form several phenomenological studies of 0
νββ
in the presence of sterile neutrinos with and without higher-dimensional operators. We find that non-standard interactions involving sterile neutrinos have a dramatic impact on 0
νββ
phenomenology, and next-generation experiments can probe such interactions up to scales of
O
(100) TeV.
Flexible barriers undergo large deformation to extend the impact duration, and thereby reduce the impact load of geophysical flows. The performance of flexible barriers remains a crucial challenge ...because there currently lacks a comprehensive criterion for estimating impact load. In this study, a series of centrifuge tests were carried out to investigate different geophysical flow types impacting an instrumented flexible barrier. The geophysical flows modelled include covered in this study include flood, hyperconcentrated flow, debris flow, and dry debris avalanche. Results reveal that the relationship between the Froude number,
Fr
, and the pressure coefficient
α
strongly depends on the formation of static deposits called dead zones which induce static loads and whether a run-up or pile-up impact mechanism develops. Test results demonstrate that flexible barriers can attenuate peak impact loads of flood, hyperconcentrated flow, and debris flow by up to 50% compared to rigid barriers. Furthermore, flexible barriers attenuate the impact load of dry debris avalanche by enabling the dry debris to reach an active failure state through large deformation. Examination of the state of static debris deposits behind the barriers indicates that hyperconcentrated and debris flows are strongly influenced by whether excessive pore water pressures regulate the depositional process of particles during the impact process. This results in significant particle rearrangement and similar state of static debris behind rigid barrier and the deformed full-retention flexible barrier, and thus the static loads on both barriers converge.
Zinc-Magnesium (Zn-Mg) alloy as a novel biodegradable metal holds great potential in biodegradable implant applications as it is more corrosion resistant than Magnesium (Mg). However, the mechanical ...properties, biodegradation uniformity, and cytotoxicity of Zn-Mg alloy remained as concerns. In this study, hot extrusion process was applied to Zn-1 wt % Mg (Zn-1Mg) to refine its microstructure. Effects of hot extrusion on biodegradation behavior and mechanical properties of Zn-1Mg were investigated in comparison with Mg rare earth element alloy WE43. Metallurgical analysis revealed significant grain size reduction, and immersion test found that corrosion rates of WE43 and Zn-1Mg were reduced by 35% and 57%, respectively after extrusion. Moreover, hot extrusion resulted in a much more uniform biodegradation in extruded Zn-1Mg alloy and WE43. In vitro cytotoxicity test results indicated that Zn-1Mg alloy was biocompatible. Therefore, hot extruded Zn-1Mg with homogenous microstructure, uniform as well as slow degradation, improved mechanical properties, and good biocompatibility was believed to be an excellent candidate material for load-bearing biodegradable implant application.
We investigate theoretically the Landau levels (LLs) and magneto-transport properties of phosphorene under a perpendicular magnetic field within the framework of the effective k·p Hamiltonian and ...tight-binding (TB) model. At low field regime, we find that the LLs linearly depend both on the LL index n and magnetic field B, which is similar with that of conventional semiconductor two-dimensional electron gas. The Landau splittings of conduction and valence band are different and the wavefunctions corresponding to the LLs are strongly anisotropic due to the different anisotropic effective masses. An analytical expression for the LLs in low energy regime is obtained via solving the decoupled Hamiltonian, which agrees well with the numerical calculations. At high magnetic regime, a self-similar Hofstadter butterfly (HB) spectrum is obtained by using the TB model. The HB spectrum is consistent with the LL fan calculated from the effective k·p theory in a wide regime of magnetic fields. We find the LLs of phosphorene nanoribbon depend strongly on the ribbon orientation due to the anisotropic hopping parameters. The Hall and the longitudinal conductances (resistances) clearly reveal the structure of LLs.
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