The conversion of light into free electron-hole pairs constitutes the key process in the fields of photodetection and photovoltaics. The efficiency of this process depends on the competition of ...different relaxation pathways and can be greatly enhanced when photoexcited carriers do not lose energy as heat, but instead transfer their excess energy into the production of additional electron-hole pairs through carrier-carrier scattering processes. Here we use optical pump-terahertz probe measurements to probe different pathways contributing to the ultrafast energy relaxation of photoexcited carriers. Our results indicate that carrier-carrier scattering is highly efficient, prevailing over optical-phonon emission in a wide range of photon wavelengths and leading to the production of secondary hot electrons originating from the conduction band. As hot electrons in graphene can drive currents, multiple hot-carrier generation makes graphene a promising material for highly efficient broadband extraction of light energy into electronic degrees of freedom, enabling high-efficiency optoelectronic applications. PUBLICATION ABSTRACT
Graphene plasmons promise unique possibilities for controlling light in nanoscale devices and for merging optics with electronics. We developed a versatile platform technology based on resonant ...optical antennas and conductivity patterns for launching and control of propagating graphene plasmons, an essential step for the development of graphene plasmonic circuits. We launched and focused infrared graphene plasmons with geometrically tailored antennas and observed how they refracted when passing through a two-dimensional conductivity pattern, here a prism-shaped bilayer. To that end, we directly mapped the graphene plasmon wavefronts by means of an imaging method that will be useful in testing future design concepts for nanoscale graphene plasmonic circuits and devices.
Controlling the energy flow processes and the associated energy relaxation rates of a light emitter is of fundamental interest and has many applications in the fields of quantum optics, ...photovoltaics, photodetection, biosensing and light emission. Advanced dielectric, semiconductor and metallic systems have been developed to tailor the interaction between an emitter and its environment. However, active control of the energy flow from an emitter into optical, electronic or plasmonic excitations has remained challenging. Here, we demonstrate in situ electrical control of the relaxation pathways of excited erbium ions, which emit light at the technologically relevant telecommunication wavelength of 1.5 μm. By placing the erbium at a few nanometres distance from graphene, we modify the relaxation rate by more than a factor of three, and control whether the emitter decays into electron-hole pairs, emitted photons or graphene near-infrared plasmons, confined to <15 nm from the graphene sheet. These capabilities to dictate optical energy transfer processes through electrical control of the local density of optical states constitute a new paradigm for active (quantum) photonics and can be applied using any combination of light emitters and two-dimensional materials.
A simple, fast and upscalable method is described to produce graphene/alumina (G/Al2O3) composites by spark plasma sintering (SPS) with a significant improvement on both mechanical and electrical ...properties of monolithic Al2O3. Graphene oxide (GO) was mixed with Al2O3 using a colloidal method obtaining an excellent dispersion of GO in the alumina matrix. The material was consolidated by SPS that allowed, in one-step, the in situ reduction of the GO during the sintering process. A detailed Raman analysis was found to be very useful to study the orientation of the graphene in the composite and to evaluate and optimise its thermal reduction. Graphene platelets acted as elastic bridges avoiding crack propagation and providing this material with a crack bridging reinforcement mechanism. A very low graphene loading (0.22wt%) led to a 50% improvement on the mechanical properties of the alumina and to an increase of the electrical conductivity up to eight orders of magnitude.
In the present work, the dry sliding behavior of a graphene/alumina composite material was studied against alumina in air. The tests were carried out in a reciprocating wear tester with an applied ...load of 20N, a sliding speed of 0.06ms−1 and a sliding distance of up to 10km. Under the testing conditions, the graphene/ceramic composite showed approximately half the wear rate and a 10% lower friction coefficient than the monolithic alumina. It has been found that this behavior is related to the presence of graphene platelets adhered to the surface of friction that form a self-lubricating layer which provides enough lubrication in order to reduce both wear rate and friction coefficient, as compared to the alumina/alumina tribological system.
Radial fretting is defined as the damage caused by the relative motion of a ball under a variable normal load. The conducted experimental tests proved the existence of this damage even in contacting ...bodies with similar materials and elastic properties; however, the reviewed analytical methods do not predict damage under these conditions, and the numerical methods are time-consuming, especially when the investigation requires the analysis of several loading cases or during large number of cycles. The main objective of this work was to develop a fast analytical method to analyse radial fretting wear. For this purpose, a novel formulation for contact displacements under a normal variable load was built and merged to different contact mechanic formulas. For validation purposes, false brinelling in thrust bearings was used as a representative industrial example. The results were compared with a FEM model showing a relative difference under 9% and a massive reduction of the calculation time of more than 30 000 times, moreover experimental tests were carried out, showing a good agreement between the density of friction energy and the obtained fretting damage what endorse the use of this formulation for the analysis of a large number of cycles and loading cases.
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•An analytical new formulation for radial fretting wear simulation.•An experimental and numerical validation of the proposed methodology.•An industrial application to false brinelling in stationary thrust bearings under variable loading conditions.•An alternative fretting method to FEM simulations with a massive time reduction of 30 000 times.
•Operando photoelectron spectroscopy of Ir NPs under OER conditions in aqueous electrolyte.•Electron-hole shared between Ir 5d and O 2p as key in formation active species in the OER.•DFT calculations ...of the amount of hole character in Δp and Δd depending on the oxidation state.
An electrode for the oxygen evolution reaction based on a conductive bi-layered free standing graphene support functionalized with iridium nanoparticles was fabricated and characterized by means of potentiometric and advanced X-ray spectroscopic techniques. It was found that the electrocatalytic activity of iridium nanoparticles is associated to the formation of Ir 5d electron holes. Strong Ir 5d and O 2p hybridization, however, leads to a concomitant increase O 2p hole character, making oxygen electron deficient and susceptible to nucleophilic attack by water. Consequently, more efficient electrocatalysts can be synthesized by increasing the number of electron-holes shared between the metal d and oxygen 2p.
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