A mercury emission model was developed to estimate non-point source mercury (Hg) emissions occurring over the year from the Idrijca River catchment, draining the area of the world’s second largest Hg ...mine in Idrija, Slovenia. Site-specific empirical correlations between the measured Hg emission fluxes and the parameters controlling the emission (comprising substrate Hg content, soil temperature, solar radiation and soil moisture) were incorporated into the mercury emission model developed using Geographic Information System technology. In this way, the spatial distribution and significance of the most polluted sites that need to be properly managed was assessed. The modelling results revealed that annually approximately 51 kg of mercury are emitted from contaminated surfaces in the catchment (640 km
2), highlighting that emission from contaminated surfaces contributes significantly to the elevated Hg concentrations in the ambient air of the region. Very variable meteorological conditions in the modelling domain throughout the year resulted in the high seasonal and spatial variations of mercury emission fluxes observed. Moreover, it was found that mercury emission fluxes from surfaces in the Idrija region are 3–4 fold higher than the values commonly used in models representing emissions from global mercuriferous belts. Sensitivity and model uncertainty analysis indicated the importance of knowing not only the amount but also the type of mercury species and their binding in soils in future model development.
Some general facts, uncertainties and gaps in current knowledge of Hg cycling in coastal and oceanic environments are given. As a case study the Gulf of Trieste is chosen. The Gulf is subject to ...substantial Hg pollution, originating from the Soča river, that drains the cinnabar deposits of the world’s second largest Hg mining area, Idrija, Slovenia. The Gulf belongs to one of the most polluted areas in the Mediterranean. Apart from Hg problems, the Gulf is also a subject to industrial and sewage pollution. Due to deteriorating water quality in the Gulf there is a great concern that Hg can be remobilized from sediments to the water column as well as enhance methylation rates which may consequently increase already elevated Hg levels in aquatic organisms. The paper presents data from a recent study which aims to assess the extent of contamination of the Gulf of Trieste after the closure of the Hg mine. Mercury and methylmercury were measured in various environmental compartments (estuarine and marine waters, sediments, and organisms) during the period 1995–1997. Data obtained show that even 10 years after closure of the Hg mine, Hg concentrations in river sediments and water are still very high and did not show the expected decrease of Hg in the Gulf of Trieste. A provisional annual mercury mass balance was established for the Gulf of Trieste showing that the major source of inorganic mercury is still the River Soča (Isonzo) while the major source of methylmercury is the bottom sediment of the Gulf.
► Extreme mercury soil contamination as a result of small scale ore roasting activity. ► Hg contents above 5000 mg/kg determined in several soil and SOM samples. ► About 50 % of Hg in investigated ...soil and SOM samples are potentially bioavailable.
The Idrija mine was the second largest Hg mine in the world surpassed only by the Almaden mine in Spain. It has been estimated that almost 145,000
tons of Hg was produced during operation (1490–1995) of the mine. In the first decade of Hg mining in Idrija the ore was roasted in piles; after that it was roasted for 150 years, until 1652, in earthen vessels at various sites in the woods around Idrija. Pšenk is one out of 21 localities of ancient roasting sites established on the hills surrounding Idrija and one of the largest localities of roasting vessel fragments. The unique way of roasting very rich Hg ore at this site has resulted in soil contamination and considerable amounts of waste material that potentially leach Hg into the surrounding environment. The main aim of this study was to determine the distribution and the forms of Hg in contaminated soils in order to evaluate potential environmental risk. Detailed soil sampling was performed on 37,800
m
2 area to establish the extent of Hg pollution and to investigate Hg transformations and transport characteristics through the 400 a-long period. A total of 156 soil (0–15
cm and 15–30
cm) and SOM (soil organic matter) samples were collected from 73 sampling points. Three soil profiles were sampled to determine vertical distribution of Hg. The main Hg phases were determined by the Hg-thermo-desorption technique. The measured Hg contents in soil samples in the study area vary from 5.5 to almost 9000
mg/kg with a median of 200
mg/kg. In SOM, Hg contents range from 1.4 to 4200
mg/kg with a median of 20
mg/kg. Extremely high Hg contents were found in soil profiles where the metal reaches 37,020
mg/kg. In general, Hg concentrations in all three profiles show a gradual decrease with depth with the minimum values between 140
mg/kg and 1080
mg/kg. The Hg-thermo-desorption curves indicate the presence of Hg in the form of cinnabar and that of Hg bound to organic or mineral soil matter. The distribution of Hg species in soil and SOM samples show almost equal distribution of cinnabar and non-cinnabar Hg compounds. The non-cinnabar fraction shows a little increase with depth, but cinnabar represents a high portion of total Hg (about 40%). Large amounts of potentially mobile and transformable non-cinnabar Hg compounds exist at the roasting site, which are potentially bioavailable.
The Idrija Mine is the second largest Hg mine in the world which operated for 500 years. Mercury (Hg)-laden tailings still line the banks, and the system is a threat to the Idrija River and water ...bodies downstream including the Soca/Isonzo River and the Gulf of Trieste in the northern Adriatic Sea. A multidisciplinary study was conducted in June 1998 on water samples collected throughout the Idrija and Soca River systems and waters and sediments in the Gulf. Total Hg in the Idrija River increased >20-fold downstream of the mine from <3 to >60 ng liter−1 with methyl mercury (MeHg) accounting for ∼0.5%. Concentrations increased again downstream and into the estuary with MeHg accounting for nearly 1.5% of the total. While bacteria upstream of the mine did not contain mercury detoxification genes (mer), such genes were detected in bacteria collected downstream. Benthic macroinvertebrate diversity decreased downstream of the mine. Gulf waters near the river mouth contained up to 65 ng liter−1 total Hg with ∼0.05 ng liter−1 MeHg. Gulf sediments near the river mouth contained 40 μg g−1 total Hg with MeHg concentrations of about 3 ng g−1. Hg in sediment pore waters varied between 1 and 8 ng liter−1, with MeHg accounting for up to 85%. Hg methylation and MeHg demethylation were active in Gulf sediments with highest activities near the surface. MeHg was degraded by an oxidative pathway with >97% C released from MeHg as CO2. Hg methylation depth profiles resembled profiles of dissolved MeHg. Hg-laden waters still strongly impact the riverine, estuarine, and marine systems. Macroinvertebrates and bacteria in the Idrija River responded to Hg stress, and high Hg levels persist into the Gulf. Increases in total Hg and MeHg in the estuary demonstrate the remobilization of Hg, presumably as HgS dissolution and recycling. Gulf sediments actively produce MeHg, which enters bottom waters and presumably the marine food chain.
Total Hg concentrations and Hg speciation were determined in bottom sediments of Marano lagoon to investigate the consequences of Hg phases on fish farms and shellfish cultivation areas. Mercury ...phases were separated into cinnabar (HgS) and non-cinnabar compounds, via a thermo-desorption technique, in surface and core sediments; both of which had been contaminated by industrial wastes and mining activity residues. The former are due to an industrial complex, which has been producing cellulose, chlor-alkali and textile artificial fibres since 1940. Processing and seepage wastewaters, which were historically discharged into the Aussa-Corno river system and therefore into the lagoon, have been significantly reduced since 1984 due to the construction of wastewater treatment facilities. The second source is the Isonzo River, which has been the largest contributor of Hg into the northern Adriatic Sea since the 16th century due to Hg mining at the Idrija mine (western Slovenia). Red cinnabar (HgS) derived from the mining area is mostly stable and insoluble under current environmental conditions. In contrast, organically bound Hg, such as Hg bound to humic acids, has the potential to be transformed into bioavailable Hg compounds (for example, methylmercury). The presence of the two Hg forms permitted each Hg source to be quantified. It also allowed the areas with the highest risk of Hg contamination from Hg-rich sediment to be identified; thus potentially avoiding the transfer of Hg from the sediment into the water column and eventually into living biota. The results show that Hg Enrichment Factors in bottom sediments exceed values of 10 and cinnabar dominates the central sector near the main tidal channel where tidal flux is more effective. Non-cinnabar compounds were found to be enriched in fine grained material and organic matter. In fact, up to 98% of total Hg at the Aussa-Corno river mouth and in the inner margin of the basin occurred in an organic form. This evidence, combined with the high contents of total Hg (4.1–6.6
μg
g
−1 and EF
>
10) measured in surface sediments, suggest that Hg in Marano lagoon is involved in biogeochemical transformations (e.g., methylation).
The 1511 Western Slovenia earthquake (
M
=
6.9) is the largest event occurred so far in the region of the Alps–Dinarides junction. Though it strongly influences the regional seismic hazard ...assessment, the epicenter and mechanism are still under debate. The complexity of the active tectonics of the Alps–Dinarides junction is reflected by the presence of both compressional and transpressional deformations. This complexity is witnessed by the recent occurrence of three main earthquake sequences, the 1976 Friuli thrust faulting events, the 1998 Bovec–Krn Mountain and the 2004 Kobarid strike-slip events. The epicenters of the 1998 and 2004 strike-slip earthquakes (
M
s
=
5.7 and
M
s
=
4.9, respectively) lie only 50 km far from the 1976 thrust earthquake (
M
s
=
6.5).
We use the available macroseismic data and recent active tectonics studies, to assess a possible epicenter and mechanism for the 1511 earthquake and causative fault. According with previous works reported in the literature, we analyze both a two-and a single-event case, defining several input fault models. We compute synthetic seismograms up to 1 Hz in an extended-source approximation, testing different rupture propagations and applying a uniform seismic moment distribution on the fault segments. We extract the maximum horizontal velocities from the synthetics and we convert them into intensities by means of an empirical relation. A rounded-to-integer misfit between observed and computed intensities is performed, considering both a minimized and a maximized databases, built to avoid the use of half-degree macroseismic intensity data points. Our results are consistent with a 6.9 magnitude single event rupturing 50 km of the Idrija right-lateral strike-slip fault with bilateral rupture propagation.
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