This study addresses and conceptualizes the possible dependence of ecosystem services on prevailing air and/or water flow processes and conditions, and particularly on the trajectories and associated ...spatial reach of these flows in carrying services from supply to demand areas in the landscape. The present conceptualization considers and accounts for such flow-dependence in terms of potential and actually realized service supply and demand, which may generally differ and must therefore be distinguished due to and accounting for the prevailing conditions of service carrier flows. We here concretize and quantify such flow-dependence for a specific landscape case (the Stockholm region, Sweden) and for two examples of regulating ecosystem services: local climate regulation and storm water regulation. For these service and landscape examples, we identify, quantify and map key areas of potential and realized service supply and demand, based for the former (potential) on prevailing relatively static types of landscape conditions (such as land-cover/use, soil type and demographics), and for the latter (realized) on relevant carrier air and water flows. These first-order quantification examples constitute first steps towards further development of generally needed such flow-dependence assessments for various types of ecosystem services in different landscapes over the world.
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•Quantitative distinction of potential and realized ecosystem service supply-demand•Quantification and mapping of flows of ecosystem services through the landscape•Simple and scalable quantification and mapping methodology•Local climate regulation and storm water regulation in urban and peri-urban areas
This paper presents an approach for using rich datasets to develop different building archetypes depending on the urban energy challenges addressed. Two cases (building retrofitting and electric ...heating) were analysed using the same city, Stockholm (Sweden), and the same input data, energy performance certificates and heat energy use metering data. The distinctive character of these problems resulted in different modelling workflows and archetypes being developed. The building retrofitting case followed a hybrid approach, integrating statistical and physical perspectives, estimating energy savings for 5532 buildings from seven retrofitting packages. The electric heating case provided an explicitly statistical data-driven view of the problem, estimating potential for improvement of power capacity of the local electric grid at peak electric power of 147 MW. The conclusion was that the growing availability of linked building energy data requires a shift in the urban building energy modelling (UBEM) paradigm from single-logic models to on-request multiple-purpose data intelligence services.
Persistent plastics, with an estimated lifetime for degradation of hundreds of years in marine conditions, can break up into micro- and nanoplastics over shorter timescales, thus facilitating their ...uptake by marine biota throughout the food chain. These polymers may contain chemical additives and contaminants, including some known endocrine disruptors that may be harmful at extremely low concentrations for marine biota, thus posing potential risks to marine ecosystems, biodiversity and food availability. Although there is still need to carry out focused scientific research to fill the knowledge gaps about the impacts of plastic litter in the marine environment (Wagner et al. in Environ Sci Eur 26:9,
2014
), the food chain and human health, existing scientific evidence and concerns are already sufficient to support actions by the scientific, industry, policy and civil society communities to curb the ongoing flow of plastics and the toxic chemicals they contain into the marine environment. Without immediate strong preventive measures, the environmental impacts and the economic costs are set only to become worse, even in the short term. Continued increases in plastic production and consumption, combined with wasteful uses, inefficient waste collection infrastructures and insufficient waste management facilities, especially in developing countries, mean that even achieving already established objectives for reductions in marine litter remains a huge challenge, and one unlikely to be met without a fundamental rethink of the ways in which we consume plastics. This document was prepared by a working group of Regional Centres of the Stockholm and Basel Conventions and related colleagues intended to be a background document for discussion in the 2017 Conference of the Parties (COP) of the Basel Convention on hazardous wastes and the Stockholm Convention on persistent organic pollutants (POPs). The COP finally approved that the issue of plastic waste could be dealt by its Regional Centres and consistently report their activities on the matter to next COP’s meetings.
Fluorinated chrome mist suppressants (CMSs) have been widely used in the electroplating industry globally, including China. In compliance with the Stockholm Convention on Persistent Organic ...Pollutants, China has phased out perfluorooctane sulfonate (PFOS) as CMS, except for closed-loop systems, before March 2019. Since then, several alternatives have been introduced to replace PFOS, but many of them still belong to the per- and polyfluoroalkyl substances (PFASs) family. In this study, for the first time, we collected and analyzed CMS samples from the Chinese market in 2013, 2015, and 2021 to determine their PFAS composition. For products with relatively few PFAS targets, we performed a total fluorine (TF) screening test and suspect and non-target analysis. Our findings suggest that 6:2 fluorotelomer sulfonate (6:2 FTS) has become the primary alternative on the Chinese market. Surprisingly, we identified 8:2 chlorinated polyfluorinated ether sulfonate (8:2 Cl-PFAES) as the primary ingredient in a CMS product (F–115B), which is the longer chain modification of the classical CMS product (F–53B). Furthermore, we identified three novel PFASs as PFOS alternatives, including hydrogen-substituted perfluoroalkyl sulfonates (H–PFSAs) and perfluorinated ether sulfonates (O–PFSAs). We also screened and identified six hydrocarbon surfactants in PFAS-free products as the primary ingredients. Despite this, some PFOS-based CMSs remain on the Chinese market. To prevent the opportunistic use of PFOS for illegal purposes, it is essential to enforce regulations strictly and ensure that such CMSs are used only in closed-loop chrome plating systems.
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•PFAS profiles in chrome mist suppressants (CMSs) on Chinese market were reported.•8:2 Cl-PFAES as PFOS alternative was found in a CMS sample for the first time.•Three novel PFASs were identified in CMSs samples by non-target analysis (NTA).
La conmemoración del 50º aniversario de la Conferencia de las Naciones Unidas sobre el Medio humano celebrada en Estocolmo en 1972 coincide con el 30º aniversario de la Convención Marco sobre la ...Diversidad Biológica (CBD) y con la celebración de las Conferencias de las Partes (COP) de las principales convenciones relacionadas con la biodiversidad. Esta coincidencia nos ha brindado la oportunidad de valorar la influencia de esta primera gran conferencia en la adopción de los instrumentos normativos posteriores para la protección de la biodiversidad, llevándonos a constatar que, aunque se hallen fragmentados, giran como en una constelación en torno a la CBD, de acuerdo a unos principios comunes. La celebración de Estocolmo+50 nos ha llevado a examinar los grandes retos para la protección de la biodiversidad, y cómo se abordarán en la COP15 de la CDB que tiene que adoptar el Plan Mundial para la Biodiversidad y sus Metas estratégicas para el período posterior a 2020. Entre estos grandes retos destacan no sólo la creciente pérdida de biodiversidad sino también los problemas de cumplimiento de las normas internacionales y de los planes nacionales que deberían frenarla. A pesar de las carencias de la gobernanza de la biodiversidad, aún existe la posibilidad de introducir mejoras creando sinergias entre las convenciones relativas a la biodiversidad y sus instrumentos de soft law. Por último, examinaremos la gran propuesta china de alcanzar una civilización ecológica, que haga posible hacer las paces con la naturaleza como ha propuesto el Secretario General de las Naciones Unidas, Antonio Guterres.
Persistent organic pollutants (POPs) are toxic chemicals that stay in the environment for a long time. To address the toxicity issues, global nations, including 53 African countries, ratified the ...Stockholm Convention to minimize or eliminate the production of 12 POPs known as the “Dirty Dozen”. However, these Dirty Dozen Chemicals (DDCs) still exist in significant concentration in the African environment, prompting numerous research to investigate the level of their occurrences. Here, we conducted a bibliometric analysis to examine the publication trends in DDCs-related research in Africa using articles published between 1949 and 2021 from the Web of Science and Scopus databases. A total of 884 articles were published within the survey period, with a publication/author and author/publication ratio of 0.36 and 2.76, respectively. South Africa ranked first in terms of number of publications (n = 133, 15.05%), and total citations (n = 3115), followed by Egypt (n = 117), Nigeria (n = 77), USA (n = 40), and Ghana (n = 38). Research collaboration was relatively high (collaboration index = 2.88). The insignificant difference between the theoretical and observed Lotka's distribution indicates Lotka's law does not fit the DDC literature. An annual growth rate of 0.57% implies that a substantial increase of articles in years to come is not expected. More research programs should be established in other African countries to measure up to South Africa's supremacy. This is critical in order to provide a basis for effective compliance to the Stockholm Convention on POPs in Africa.
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•884 articles were retrieved from the WoS and Scopus from 1949 to 2021.•South Africa ranked first in the majority of the bibliometric indices.•Documents indexed in WoS and Scopus were grouped into four topical domains.•Substantial research output on DDC in Africa is not likely in future.
A field experiment was conducted in Stockholm where a congestion charge trial was introduced in 2006. Respondents completed a questionnaire before and after the trial. Acceptance of the congestion ...charge was higher after the trial as opposed to its acceptability judgments before the trial. Respondents believed the charge had more positive consequences (viz., decreasing parking problems, congestion, and pollution) and less negative consequences (viz., financial cost increases) after the trial than they had expected beforehand. Furthermore, we examined the relative importance of various beliefs for the acceptability of the congestion charge before and after it was implemented. Results are that before the implementation of the charge acceptability was significantly related to beliefs about the expected consequences for one’s own car use and financial costs, whereas acceptance after the trial was related to beliefs about the perceived consequences for one’s own car use and parking problems. These results indicate that acceptance of the congestion charge had increased because people experienced positive consequences of the charge. This conclusion is discussed in the broader context in which the Stockholm trial took place.
Occurrence of benzotriazole ultraviolet stabilizers (BUVs) in different environmental matrices has attracted researchers and regulatory agencies worldwide due to its persistency, bioaccumulative and ...toxic properties. Environmental occurrence of BUVs in Indian freshwater is lacking. The present study analyzed six targeted BUVs in surface water and sediments of three rivers of Central India. BUVs were determined in pre- and post-monsoon seasons to reveal their concentration, spatio-temporal distribution and probable ecological risks. Results indicated that total concentration of BUVs (ƩBUVs) ranged from ND to 42.88 μg/L in water, and ND to 165.26 ng/g in sediments with UV-329 as the predominant BUV in surface water and sediments during pre- and post-monsoon seasons. Surface water samples from Pili River, and sediment of Nag River accounted for maximum BUVs concentration. Partitioning coefficient results confirmed the effective transfer of BUVs from overlaying water to sediments. The observed concentration of BUVs in water and sediments posed low ecological risk to planktons. Untreated municipal discharges and poor waste management practices including dumping of wastes might be the sources of BUVs in water bodies.
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•First evidence on the environmental occurrence of six BUVs in Indian water bodies•UV-329 and UV-327 were the dominant BUVs in sediment and water.•Pseudo partitioning coefficient reveals the release from BUVs from sediment to water.•BUVs posed low risk to planktons in water bodies.•Plastic debris and wastewater discharge were major sources of BUVs.
Decabromodiphenyl ether (Deca-BDE) was officially listed in Annex A of the Stockholm Convention for persistent organic pollutants (POPs). It is necessary to establish its emission inventory to help ...reduce Deca-BDE contamination in the environment. We established a comprehensive Deca-BDE emission inventory in China. The results reveal that, from 2015 to 2017, the Deca-BDE emissions in its production source (source I) were less altered but increased annually in flame retarded plastics processing (source II), Deca-BDE-containing products usage (source III), and electronic waste (e-waste) treatment (source IV). We show that Deca-BDE emissions declined significantly in sources I and II but grew in source III and source IV from 2017 to 2018. We set up the provincial emission inventory to a gridded map on a spatial resolution of 0.25°× 0.25° latitude/longitude. The gridded inventory was incorporated into ChnMETOP model to simulate Deca-BDE concentrations in air and soil, and the modeled concentrations were compared to field-sampling data. The results show that the Deca-BDE emission inventory developed in this study agreed well with observed data, demonstrating that the Deca-BDE inventory in China developed in the present study is reliable. The inventory provides a support for quantifying human exposure risk to Deca-BDE and developing effective mitigation measures to mitigate Deca-BDE emissions.
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•Deca-BDE emissions occurred mainly in eastern and southeastern China.•A significant reduction of Deca-BDE emissions in China was identified after the 2017.•ChnMETOP simulations of Deca-BDE were performed using Deca-BDE emissions.•Deca-BDE emissions were verified by comparing modeled and measured concentrations.
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