Atomically dispersed Zn–N–C nanomaterials are promising platinum‐free catalysts for the oxygen reduction reaction (ORR). However, the fabrication of Zn–N–C catalysts with a high Zn loading remains a ...formidable challenge owing to the high volatility of the Zn precursor during high‐temperature annealing. Herein, we report that an atomically dispersed Zn–N–C catalyst with an ultrahigh Zn loading of 9.33 wt % could be successfully prepared by simply adopting a very low annealing rate of 1° min−1. The Zn–N–C catalyst exhibited comparable ORR activity to that of Fe–N–C catalysts, and significantly better ORR stability than Fe–N–C catalysts in both acidic and alkaline media. Further experiments and DFT calculations demonstrated that the Zn–N–C catalyst was less susceptible to protonation than the corresponding Fe–N–C catalyst in an acidic medium. DFT calculations revealed that the Zn–N4 structure is more electrochemically stable than the Fe–N4 structure during the ORR process.
Slow and steady wins the race: An atomically dispersed Zn–N–C catalyst with an ultrahigh loading of single Zn atoms of 9.33 wt % (see HAADF‐STEM image) was successfully prepared by decreasing the annealing rate to 1° min−1. The Zn–N–C catalyst exhibited comparable ORR activity to that of the corresponding Fe–N–C catalyst, and greater ORR stability in both acidic and alkaline media.
The advent of SiC devices which results in lower rise times and steep <inline-formula> <tex-math notation="LaTeX">\text{d}v/\text{d}t </tex-math></inline-formula> at the inverter terminal can ...compromise the common mode (CM)-conducted emissions' compliance, motor peak ac -CM currents, and leakage currents. Consequently, this results in a high ac and dc side CM filter weight. AC filters at the inverter output terminal are effective in reducing the slew rate of inverter voltage thereby reducing the peak CM current. However, a special case with high <inline-formula> <tex-math notation="LaTeX">\text{d}v/\text{d}t </tex-math></inline-formula> arising from low duty cycles is found to increase the peak ac-CM current significantly. Reduced CM voltage (CMV) schemes are popular pulsewidth modulation (PWM) methods to minimize the peak CMV but suffer from high <inline-formula> <tex-math notation="LaTeX">\text{d}v/\text{d}t </tex-math></inline-formula> under this special case as well. In this article, a staggered PWM scheme to minimize such peak ac -CM currents for a high-speed variable frequency drive (VFD) is evaluated using a three-level SiC-based T-type inverter as a demonstrator. From the analysis, the proposed switching pattern shows benefits over conventional sinusoidal PWM (SPWM) scheme and is found to be scalable to other PWM schemes and voltage levels. Simulation and experimental results are shown to validate the performance of the proposed switching pattern.
We construct a new analytic phenomenological model for the extended circumgalactic material (CGM) of L* galaxies. Our model reproduces the O vii/O viii absorption observations of the Milky Way (MW) ...and the O vi measurements reported by the COS-Halos and eCGM surveys. The warm/hot gas is in hydrostatic equilibrium in an MW gravitational potential, and we adopt a barotropic equation of state, resulting in a temperature variation as a function of radius. A pressure component with an adiabatic index of is included to approximate the effects of a magnetic field and cosmic rays. We introduce a metallicity gradient motivated by the enrichment of the inner CGM by the Galaxy. We then present our fiducial model for the corona, tuned to reproduce the observed O vi-O viii column densities and with a total mass of inside . The gas densities in the CGM are low ( cm−3), and its collisional ionization state is modified by the metagalactic radiation field. We show that for O vi-bearing warm/hot gas with typical observed column densities cm−2 at large ( kpc) impact parameters from the central galaxies, the ratio of the cooling to dynamical times, / , has a model-independent upper limit of . In our model, / at large radii is . We present predictions for a wide range of future observations of the warm/hot CGM, from UV/X-ray absorption and emission spectroscopy to dispersion measure and Sunyaev-Zel'dovich cosmic microwave background measurements. We provide the model outputs in machine-readable data files for easy comparison and analysis.
High-entropy alloys (HEAs) are an intriguing new class of metallic materials due to their unique mechanical behavior. Achieving a detailed understanding of structure–property relationships in these ...materials has been challenged by the compositional disorder that underlies their unique mechanical behavior. Accordingly, in this work, we employ first-principles calculations to investigate the nature of local chemical order and establish its relationship to the intrinsic and extrinsic stacking fault energy (SFE) in CrCoNi medium-entropy solid-solution alloys, whose combination of strength, ductility, and toughness properties approaches the best on record. We find that the average intrinsic and extrinsic SFE are both highly tunable, with values ranging from −43 to 30 mJ·m−2 and from −28 to 66 mJ·m−2, respectively, as the degree of local chemical order increases. The state of local ordering also strongly correlates with the energy difference between the face-centered cubic (fcc) and hexagonal close-packed (hcp) phases, which affects the occurrence of transformation-induced plasticity. This theoretical study demonstrates that chemical short-range order is thermodynamically favored in HEAs and can be tuned to affect the mechanical behavior of these alloys. It thus addresses the pressing need to establish robust processing–structure–property relationships to guide the science-based design of new HEAs with targeted mechanical behavior.
Structured lipid is a type of modified form of lipid that is "fabricated" with the purpose to improve the nutritional and functional properties of conventional fats and oils derived from animal and ...plant sources. Such healthier choice of lipid received escalating attention from the public for its capability to manage the rising prevalence of metabolic syndrome. Of which, medium-chain triacylglycerol (MCT) and medium-and long-chain triacylglycerol (MLCT) are the few examples of the "new generation" custom-made healthful lipids which are mainly composed of medium chain fatty acid (MCFA). MCT is made up exclusively of MCFA whereas MLCT contains a mixture of MCFA and long chain fatty acid (LCFA), respectively. Attributed by the unique metabolism of MCFA which is rapidly metabolized by the body, MCFA and MCT showed to acquire multiple physiological and functional properties in managing and reversing certain health disorders. Several chemically or enzymatically oils and fats modification processes catalyzed by a biological or chemical catalyst such as acidolysis, interesterification and esterification are adopted to synthesis MCT and MLCT. With their purported health benefits, MCT and MLCT are widely being used as nutraceutical in food and pharmaceutical sectors. This article aims to provide a comprehensive review on MCT and MLCT, with an emphasis on the basic understanding of its structures, properties, unique metabolism; the current status of the touted health benefits; latest routes of production; its up-to-date applications in the different food systems; relevant patents filed and its drawbacks
Aims.
We present the joint analysis of the X-ray and Sunyaev–Zel’dovich (SZ) signals in Abell 2319, the galaxy cluster with the highest signal-to-noise ratio in SZ
Planck
maps and that has been ...surveyed within our
XMM-Newton
Cluster Outskirts Project (X-COP), a very large program which aims to grasp the physical condition in 12 local (
z
< 0.1) and massive (
M
200
> 3 × 10
14
M
⊙
) galaxy clusters out to
R
200
and beyond.
Methods.
We recover the profiles of the thermodynamic properties by the geometrical deprojection of the X-ray surface brightness, of the SZ Comptonization parameter, and accurate and robust spectroscopic measurements of the gas temperature out to 3.2 Mpc (1.6
R
200
), 4 Mpc (2
R
200
), and 1.6 Mpc (0.8
R
200
), respectively. We resolve the clumpiness of the gas density to be below 20% over the entire observed volume. We also demonstrate that most of this clumpiness originates from the ongoing merger and can be associated with large-scale inhomogeneities (the “residual” clumpiness). We estimate the total mass through the hydrostatic equilibrium equation. This analysis is done both in azimuthally averaged radial bins and in eight independent angular sectors, enabling us to study in detail the azimuthal variance of the recovered properties.
Results.
Given the exquisite quality of the X-ray and SZ datasets, their radial extension, and their complementarity, we constrain at
R
200
the total hydrostatic mass, modelled with a Navarro–Frenk–White profile at very high precision (
M
200
= 10.7 ± 0.5
stat.
± 0.9
syst.
× 10
14
M
⊙
). We identify the ongoing merger and how it is affecting differently the gas properties in the resolved azimuthal sectors. We have several indications that the merger has injected a high level of non-thermal pressure in this system: the clumping free density profile is above the average profile obtained by stacking Rosat/PSPC observations; the gas mass fraction recovered using our hydrostatic mass profile exceeds the expected cosmic gas fraction beyond
R
500
; the pressure profile is flatter than the fit obtained by the Planck Collaboration; the entropy profile is flatter than the mean profile predicted from non-radiative simulations; the analysis in azimuthal sectors has revealed that these deviations occur in a preferred region of the cluster. All these tensions are resolved by requiring a relative support of about 40% from non-thermal to the total pressure at
R
200
.
Herein, we present a new strategy for the synthesis of 2D porous MoP/Mo2N heterojunction nanosheets based on the pyrolysis of 2D PMo12O403−‐melamine (PMo12‐MA) nanosheet precursor from a polyethylene ...glycol (PEG)‐mediated assembly route. The heterostructure nanosheets are ca. 20 nm thick and have plentiful pores (<5 nm). These structure features offer advantages to promote the HER activity, including the favorable water dissociation kinetics around heterojunction as confirmed by theoretical calculations, large accessible surface of 2D nanosheets, and enhanced mass‐transport ability by pores. Consequently, the 2D porous MoP/Mo2N heterojunction nanosheets exhibit excellent HER activity with low overpotentials of 89, 91 and 89 mV to achieve a current density of 10 mA cm−2 in alkaline, neutral and acidic electrolytes, respectively. The HER performance is superior to the commercial Pt/C at a current density >55 mA cm−2 in neutral medium and >190 mA cm−2 in alkaline medium.
2D porous MoP/Mo2N heterojunction nanosheets have been created based on a PEG‐mediated assembly strategy, which exhibit outstanding performance for HER over wide pH ranges even out‐performing the Pt/C benchmark at large current density. A series of tests and DFT calculations shows the synergy of the heterojunctions, pores and 2D nanosheets for promoting the HER performance.
The protagonists of the last great phase transition of the universe-cosmic reionization-remain elusive. Faint star-forming galaxies are leading candidates because they are found to be numerous and ...may have significant ionizing photon escape fractions ( ). Here we update this picture via an empirical model that successfully predicts latest observations (e.g., the rapid drop in star-formation density ( at ). We generate an ionizing spectrum for each galaxy in our model and constrain by leveraging latest measurements of the reionization timeline (e.g., Ly damping of quasars and galaxies at z > 7). Assuming a constant across all sources at z > 6, we find < −13.5 galaxies need = to complete reionization. The inferred Intergalactic Medium neutral fraction is 0.9, 0.5, 0.1 at -that is, the bulk of reionization transpires rapidly in 300 Myr, driven by the z > 8 SFR and favored by high neutral fractions (∼60%-90%) measured at z ∼ 7-8. Inspired by the emergent sample of Lyman Continuum (LyC) leakers spanning z ∼ 0-6.6 that overwhelmingly displays higher-than-average star-formation surface density ( ), we propose a physically motivated model relating to and find . Since falls by ∼2.5 dex between z = 8 and z = 0, our model explains the humble upper limits on at lower redshifts and its required evolution to ∼ 0.2 at z > 6. Within this model, strikingly, <5% of galaxies with < −18 and log(M /M ) > 8 (the "oligarchs") account for 80% of the reionization budget-a stark departure from the canonical "democratic" reionization led by copious faint sources. In fact, faint sources ( > −16) must be relegated to a limited role in order to ensure high neutral fractions at z = 7-8. Shallow faint-end slopes of the UV luminosity function ( > −2) and/or distributions skewed toward massive galaxies produce the required late and rapid reionization. We predict that LyC leakers like COLA1 (z = 6.6, ∼ 30%, = −21.5) will become increasingly common toward z ∼ 6 and that the drivers of reionization do not lie hidden across the faint end of the luminosity function but are already known to us.
This study seeks to make a contribution to our conceptual and empirical understanding into the nature of talent management (TM) in German small and medium-sized enterprises (SMEs), an ...under-researched area in the field. The approach of this investigation recognizes that TM may vary significantly between different types of companies and national contexts. The findings are based on data collected from 700 SMEs in Germany. Three distinct clusters of TM intensity profiles are identified (highly engaged talent managers, reactive talent managers and retention-based talent managers), which vary according to annual sales volumes, industry affiliations, cooperative behavior with respect to human resource (HR) and TM networks, the long-term focus of TM and future HR and TM budgets. In summary, most of the investigated companies place a high importance on TM reflecting a developmental approach which fits well with the German business system. One key finding of the study was the preference of most German SMEs to choose a more inclusive approach to TM and target all or most employees, in contrast to large multinational enterprises where a more elitist approach is favored. Another major finding was that TM cooperation with other firms and institutions was used as a strategy to cope with the war for talent in a country, which despite the Global Financial Crisis is characterized by strong economic growth and important demographic challenges. Based on these findings and the contextual approach to TM, a comprehensive agenda for future research areas in TM is outlined.
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