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Univerzitetna knjižnica Maribor (UKM)
Knjižnica je med tednom odprta od 8. do 19. ure, ob sobotah od 9. do 13. ure. Čitalnica ČUK je odprta od ponedeljka do sobote od 9. do 24. ure, ob nedeljah od 16. do 24. ure. Informacije: 02 25 07 431, ukm@um.si
  • Formation of a Silylated 1-Silaallene via an Intermediate 1-Chloro-1-silaallene
    Spirk, Stefan ...
    Twofold conjugate addition to a 2,6-dimesitylphenyl-substituted dihaloalkynylsilane yields a silylsubstituted 1-silaallene rather than the isomeric silyne. The dehalogenative intramolecular ... carbometalation eliminationusing t-BuLi proceeds via stepwise dehalogenation involving an intermediate 1-chloro-1- silaallene. Our findings are backed by crystal structure analyses, spectroscopic data, and ab initio calculations. The completely dehalogenated 1-silaallene provides a silyl group at the silaallene core it self, which should allow further functionalization.
    Vir: Organometallics. - ISSN 0276-7333 (Vol. 29, issue 13, 2010, str. 2981-2986)
    Vrsta gradiva - članek, sestavni del
    Leto - 2010
    Jezik - angleški
    COBISS.SI-ID - 68797185

    Povezava(-e):

    http://pubs.acs.org/toc/orgnd7/29/13
    DOI

vir: Organometallics. - ISSN 0276-7333 (Vol. 29, issue 13, 2010, str. 2981-2986)

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