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  • A dual channel rhodamine ap...
    Sada, Pawan Kumar; Bar, Amit; Jassal, Amanpreet Kaur; Singh, Alok Kumar; Singh, Laxman; Rai, Abhishek

    Analytica chimica acta, 07/2023, Letnik: 1263
    Journal Article

    A new rhodamine-6G hydrazone RHMA has been synthesized using rhodamine-6G hydrazide and 5-Allyl-3-methoxysalicylaldehyde. RHMA has been fully characterized with different spectroscopic methods and single crystal XRD. RHMA can selectively recognize Cu2+ and Hg2+ in aqueous media amongst other common competitive metal ions. A significant change in absorbance was observed with Cu2+ and Hg2+ ions with emergence of a new peak at λmax 524 nm and 531 nm respectively. Hg2+ ions lead to “turn-on” fluorescence enhancement at λmax 555 nm. This event of absorbance and fluorescence marks the opening of spirolactum ring causing visual color change from colorless to magenta and light pink.RHMA-Cu2+ and RHMA- Hg2+complexes are found to be reversible in presence of EDTA2−ions. RHMA has real application in form of test strip. Additionally, the probe exhibits turn-on readout-based sequential logic gate-based monitoring of Cu2+ and Hg2+ at ppm levels, which may be able to address real-world challenges through simple synthesis, quick recovery, response in water, “by-eye” detection, reversible response, great selectivity, and a variety of output for accurate investigation. Display omitted •A new rhodamine hydrazone (RHMA) is synthesized and characterized using physicochemical and X-ray diffraction techniques.•RHMA shows fast and selective detection of Cu2+and Hg2+ ions.•The recognition behavior is found to be reversible with EDTA ions.•RHMA has practical application in form of paper strip test.•Sequential logic gates and keypad locks were constructed by inputs Cu2+, Hg2+ and EDTA.