Display omitted •COMSOL Multiphysics reveal the electric field distribution of synthetic samples.•Discharge channel developed along the magnetite edge and retains the complete form.•Magnetite alters the distribution state of electric field within synthetic samples.•Quartz particles hinders the development of certain discharge channels. Herein, COMSOL Multiphysics is proposed to discuss the electric field distribution of synthetic sample during the high voltage pulse discharge crushing. The pulses number required for high voltage pulse discharge to crush the synthetic sample filled with magnetite is lower than that required for quartz-filled samples. The embedding mode that the magnetite is located on the central line between the high voltage electrode and the grounding electrode of the synthetic sample is most conducive to electrical breakdown of synthetic sample. The discharge channel developed along the magnetite edge and retains the complete crystal form of magnetite. Differences in dielectric constants are responsible for variations in electric field distribution. Magnetite alters the distribution state of electric field within synthetic samples to derive higher electric field intensity and more extensive areas with high electric field intensity. The peak electric field intensity at the interface of magnetite particles is higher than that of quartz. The presence of quartz particles hinders the development of certain discharge channels.