Based on the data of 1882 Chinese doctoral students in social science fields, this study examined the initial placement of PhD holders in the academic labor market. Findings indicate the research network of doctorate holders is significantly related to their academic career identity attainment. There was an inverted U-shape curve between the research network scale and the probability of pursuing an academic career. Those occupying more structural hole locations were more likely to choose an academic career. However, neither the scale nor location of the research network could guarantee a faculty position in a prestigious university or department. No significant correlation was found between the research network and academic career status attainment.