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Khan, Zamir S.; Khan, Arsala; Lokhande, M. P.; Deshmukh, Avadhut; Kumbharkhane, A. C.
Ferroelectrics, 2/17/2022, Letnik: 588, Številka: 1Journal Article
The Complex permittivity spectra of glycol ether (GE) compounds such as ethylene glycol mono-methyl ether (EGME), ethylene glycol ethyl ether (EGEE) and ethylene glycol butyl ether (EGBE) with water mixture over entire concentration range and at 25 °C has been determined using Time Domain Reflectometry technique in the frequency range 10 MHz to 50 GHz. The complex permittivity spectra for GE-water were fitted in Cole-Davidson model. The Static dielectric constant (ε 0 ), Relaxation time (τ), effective Kirkwood correlation factor (g eff ), excess permittivity ( ) and Bruggeman factor (f B ) have been calculated by non-linear least square fit method. The intermolecular interactions between GE-water binary mixtures suggest the non-linear behavior of dielectric parameters. The contribution of hydrogen bonding interactions among the solute-solvent mixtures is confirmed by Excess properties and Bruggeman factor.
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