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Gietter-Burch, Amber A S; Devannah, Vijayarajan; Watson, Donald A
Organic letters, 06/2017, Letnik: 19, Številka: 11Journal Article
Using a commercially available Umemoto's reagent, the metal-free trifluoromethylation of nitroalkanes is now possible. This method provides a general, high-yielding synthesis of α-(trifluoromethyl)nitroalkanes. The quaternary α-(trifluoromethyl)nitroalkanes obtained from this transformation can be elaborated to a variety of complex nitrogen-containing molecules, including α-(trifluoromethyl)amines.
