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Noble, Adam; McCarver, Stefan J; MacMillan, David W. C
Journal of the American Chemical Society, 01/2015, Letnik: 137, Številka: 2Journal Article
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple hydrocarbon-substituted acids. Diverse vinyl iodides and bromides give rise to vinylation products in high efficiency under mild, operationally simple reaction conditions.
