Triboelectrochemical techniques use an electrochemical set-up (mainly of the three-electrode type) for controlling the potential of the surface of a conducting material subjected to rubbing in a tribometer. In this way it is possible to carry out friction and wear tests in electrolytic solutions under well-defined chemical conditions determined by the applied electrode potential. In addition, triboelectrochemical techniques offer the possibility of following in-situ and in real time the kinetics of electrochemical oxidation reactions (corrosion) by the simple measure of an electrical current. In the present study triboelectrochemical experiments were carried out on sputter deposited TiN coatings sliding against alumina in a borate solution (pH 8.4). The surface of selected worn coatings was characterised by X-ray photoelectron spectroscopy (XPS) and the topography by scanning electron microscopy (SEM). Results show that the rate of wear critically depends on the prevailing (electro)chemical conditions which determine the chemical surface state of the TiN coating. The behaviour is attributed to the lubricating properties of surface oxide films having a thickness in the nanometre range.