Kinetic Studies of the Chirality Inversion of Salicylaldiminato-Ruthenium Using Racemic [eta]6-p-Cymene Complexes as a Mechanistic Probe

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Kinetic Studies of the Chirality Inversion of Salicylaldiminato-Ruthenium Using Racemic [eta]6-p-Cymene Complexes as a Mechanistic Probe

Komiya, Naruyoshi; Nakajima, Tomoko; Hotta, Masato; Maeda, Takatoshi; Matsuoka, Tatsuya; Kawamorita, Soichiro; Naota, Takeshi

European journal of inorganic chemistry, 07/2016, Letnik: 2016, Številka: 19

Journal Article

Kinetic studies of the chirality inversion of a series of mono- and bimetallic (p-cymene)(salicylaldiminato)RuII complexes with halo ligands (1and 2) in solution have been performed by means of the line-shape method, using 1H NMR spectroscopy to evaluate the signal exchange rates between diastereotopic protons in the p-cymene ligand. The activation parameters (DeltaHdouble dagger and DeltaSdouble dagger) associated with the flipping molecular mobility were determined from variable-temperature NMR analyses, and it was found that the neutral halo complexes 1 and 2 exhibit much lower enthalpies and entropies than the corresponding cationic pyridine analogues 3.

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Leto	Faktor vpliva		Izdaja		Kategorija		Razvrstitev
Leto	JCR	SNIP	JCR	SNIP	JCR	SNIP	JCR	SNIP

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