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Guan-qun Zhong; Qing-hua Duan; Kui-lin Deng; Ai-qin Zhang; Ping Xie; Hai-liang Zhang; Rong-ben Zhang
高分子科学（英文版）, 2006, Letnik: 24, Številka: 1Journal Article
O63; A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane (ALPHS) was first synthesized by an amido H-bonding self-assembled template. ALPHS with molecular weight M-n = 18300 has very highly ordered ladderlike structure, which was confirmed by a sharp resonance absorption peak of -Si(H)O2/2 moiety with the half peak width A1/2 ＜ 0.5 in 29Si-NMR spectrum. Presence of the reactive Si-H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si-H reactions such as hydrosilylation, condensation, and so on.
