The complex physical, kinematic, and chemical properties of galaxy centres make them interesting environments to examine with molecular line emission. We present new 2 − 4″ (∼75 − 150 pc at 7.7 Mpc) observations at 2 and 3 mm covering the central 50″ (∼1.9 kpc) of the nearby double-barred spiral galaxy NGC 6946 obtained with the IRAM Plateau de Bure Interferometer. We detect spectral lines from ten molecules: CO, HCN, HCO + , HNC, CS, HC 3 N, N 2 H + , C 2 H, CH 3 OH, and H 2 CO. We complemented these with published 1 mm CO observations and 33 GHz continuum observations to explore the star formation rate surface density Σ SFR on 150 pc scales. In this paper, we analyse regions associated with the inner bar of NGC 6946 – the nuclear region (NUC), the northern (NBE), and southern inner bar end (SBE) and we focus on short-spacing corrected bulk (CO) and dense gas tracers (HCN, HCO + , and HNC). We find that HCO + correlates best with Σ SFR , but the dense gas fraction ( f dense ) and star formation efficiency of the dense gas (SFE dense ) fits show different behaviours than expected from large-scale disc observations. The SBE has a higher Σ SFR , f dense , and shocked gas fraction than the NBE. We examine line ratio diagnostics and find a higher CO(2−1)/CO(1−0) ratio towards NBE than for the NUC. Moreover, comparison with existing extragalactic datasets suggests that using the HCN/HNC ratio to probe kinetic temperatures is not suitable on kiloparsec and sub-kiloparsec scales in extragalactic regions. Lastly, our study shows that the HCO + /HCN ratio might not be a unique indicator to diagnose AGN activity in galaxies.