A numerical model of heat transfer was developed to investigate the heat transfer of continuously cast billet with the aid of surface temperature tests by ThermaCAM™ researcher and nail shooting experiments. The effects of secondary cooling practice and casting speed on the solidification process and central segregation of carbon were investigated as well with the actual central segregation tests. The results show that the surface center and billet center temperatures exhibit a different pattern during solidification, and the solidified shell thickness is presented as an “S” type. With the increase of secondary cooling intensity and the decrease of casting speed, the end points of the solidus line and the liquidus line move forward, and the central segregation level of carbon decreases. The optimal casting condition is suggested for continuously cast high carbon billet with F-EMS (final electromagnetic stirring).