As interfaces play a more important role in high-volume-fraction ceramic/metal composites because of containing more hetero-phase interfaces, it is a great challenge to control the interfaces in such composites to balance their strength and plasticity and to obtain high performances. In this work, 50–60 vol% (TiC + TiB2)/Al composites were fabricated in Al–Ti–B4C system via a one-step method of reaction and densification, and their interface bonding and mechanical properties were compared with those of in-situ TiC/Al composites. Apparently, the defects, such as interfacial discontinuity, macro-pores, coarsening and agglomeration of particles, caused by increased ceramic content in the TiC/Al composites, are eliminated in the (TiC + TiB2)/Al composites using Al–Ti–B4C system. The 60 vol% (TiC + TiB2)/Al composite exhibits significantly enhanced mechanical properties, i.e. 70.5%, 60.7% and 69.8% respectively higher yield strength, ultimate compressive strength and plastic strain than 60 vol% TiC/Al composite. Such enhanced mechanical properties are attributed to the improvement in interface bonding strength and therefore the increase in the energy dissipation of crack propagation. The formation of enhanced interface in the (TiC + TiB2)/Al composites results from the reduction in the reaction heat in the Al–Ti–B4C system, improved crystallographic match and improved adhesion work between ceramic particles and matrix. This work may provide a new idea for the design and control of interfaces in high-volume-fraction ceramic-metal composites. •High-volume-fraction (TiC + TiB2)/Al composites with enhanced property were fabricated.•Interface between ceramic and matrix is designed by lattice match and adhesion work.•Al–Ti–B4C reaction system is used to control the interface formation in the composite.•(TiC + TiB2)/Al composite has significantly improved performance than TiC/Al composite.•A new idea is provided for design and control interfaces in ceramic/metal composite.