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  • Ion-Beam Synthesis of Struc...
    Vakhitov, Iskander R; Lyadov, Nikolay M; Vdovin, Vladimir I; Gutakovskii, Anton K; Nuzhdin, Vladimir I; Tagirov, Lenar R; Khaibullin, Rustam I

    Crystals (Basel), 02/2023, Letnik: 13, Številka: 2
    Journal Article

    Magnetic nanoparticles embedded into semiconductors have current perspectives for use in semiconducting spintronics. In this work, 40 keV Fesup.+ ions were implanted in high fluences of (0.5 ÷ 1.5) × 10sup.17 ion/cmsup.2 into an oxide semiconductor and single-crystalline TiOsub.2 plates of rutile structure with (100) or (001) face orientations. Microstructure, elemental-phase composition, and magnetic properties of the Fe-ion-implanted TiOsub.2 were studied by scanning and transmission electron microscopies (SEM and TEM), X-ray photoelectron (XPS) and Rutherford backscattering (RBS) spectroscopies, as well as vibrating-sample magnetometry (VSM). The high-fluence ion implantation results in the formation of magnetic nanoparticles of metallic iron beneath the irradiated surface of rutile. The induced ferromagnetism and observed two- or four-fold magnetic anisotropy are associated with the endotaxial growth of Fe nanoparticles oriented along the crystallographic axes of TiOsub.2.